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<meta content="Oxygen isotope composition of the Denchai sapphire, Thailand: a clue to its enigmatic origin" name="eprints.title" />
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<meta content="Alluvial gem sapphires from the Denchai area, northern Thailand, have O-isotope compositions ranging from + 4.7 per mil to + 6.1 per mil(15 samples), with one outlier, + 8.4 per mil. It is suggested that these sapphires are not in O-isotope equilibrium with and must be xenocrysts from the nearby alkali basalts, which contain olivine phenocrysts with delta 18 O= + 4.9 per mil to + 5.1 per mil and are the presumed sources of these gem sapphires. Homogeneous delta 18 O values within individual sapphire crystal indicate limited interactions with the carrier magmas during transport to the surface. The O-isotope compositions of these sapphires suggest that crustal rocks might have been involved in the genesis of those sapphires with delta 18 O values higher than + 5.5 per mil. A hybrid origin model for the Denchai sapphires is, therefore, postulated, which involves different degrees of interactions between a fractionated partial melt from (metasomatized) mantle and a lower/mid-crust Al-rich rock." name="eprints.abstract" />
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<meta content="Aspen, P., Upton, B.G.J., Dicken, A.P., 1990. Anorthoclase, sanidine and associated megacrysts in Scottish alkali basalts: high pressure syenitic debris from upper mantle sources? Eur. J. Mineral. 2, 503-517.
Baker, J.A., MacPherson, C.G., Menzies, M.A., Thirlwall, M.F., Al-Kadasi, M., Mattey, D.P., 2000. Resolving crustal and mantle contributions to continental flood volcanism, Yemen: constraints from mineral oxygen isotope data. J. Petrol. 41, 1805-1820.
Barr, S.M., Macdonald, A.S., 1979. Palaeomagnetism, age, and
geochemistry of the Denchai basalt, northern Thailand. Earth
Planet. Sci. Lett. 46, 113-124.
Barron, L.M., Lishmund, S.R., Oakes, G.M., Barron, B.J., Sutherland, F.L., 1996. Subduction model for the origin of some diamonds in the Phanerozoic of eastern New South Wales. Aust. J. Earth Sci. 43, 257-267.
Berg, R.B., 2000. Corundum megacrysts and corundum-bearing
xenoliths in the French Bar dike, Lewis and Clark County,
Montana. Abstr. - Geol. Soc. Am. 32, 2.
Chazot, G., Lowry, D., Menzies, M., Mattey, D., 1997. Oxygen
isotopic composition of hydrous and anhydrous mantle peridotites. Geochim. Cosmochim. Acta 61, 161-169.
Coenraads, R.R., Sutherland, F.L., Kinny, P.D., 1990. The origin of sapphires: U-Pb dating of zircon inclusions sheds new light. Mineral. Mag. 54, 113-122.
Coenraads, R.R., Vichit, P., Sutherland, F.L., 1995. An unusual sapphire-zircon-magnetite xenolith from the Chanthaburi Gem Province, Thailand. Mineral. Mag. 59, 465-479.
Deines, P., 1989. Stable isotope variations in carbonatites. In: Bell, K. (Ed.), Carbonatites: Genesis and Evolution. Unwin Hyman, London, pp. 301-359.
Deines, P., Haggerty, S.E., 2000. Small-scale oxygen isotope variations and petrochemistry of ultradeep (>300 km) and transition zone xenoliths. Geochim. Cosmochim. Acta 64, 117-131.
Eiler, J.M., 2001. Oxygen isotope variations of basaltic lavas and upper mantle rocks. In: Valley, J.W., Cole, D.R. (Eds.), Stable Isotope Geochemistry. Rev. Mineral. Geochem., vol. 43. Mineralogical Society of America, Washington, DC, pp. 319-364.
Eiler, J.M., Farley, K.A., Valley, J.W., Hauri, E., Craig, H., Hart, S.R., Stolper, E.M., 1997. Oxygen isotope variations in ocean island basalt phenocrysts. Geochim. Cosmochim. Acta 61, 2281-2293.
Guo, J., OReilly, S.Y., Griffin, W.L., 1996. Corundum from basaltic terrains: a mineral inclusion approach to the enigma. Contrib. Mineral. Petrol. 122, 368-386.
Harris, C., 1995. Oxygen isotope geochemistry of the Mesozoic anorogenic complexes of Damaraland, northwest Namibia: evidence for crustal contamination and its effect on silica saturation. Contrib. Mineral. Petrol. 122, 308-321.
Hoefs, J., 1997. Stable Isotope Geochemistry, 4th ed. Springer-Verlag, Berlin. 201 pp.
Irving, A.J., 1974. Megacrysts from the Newer Basalts and other basaltic rocks of southeastern Australia. Geol. Soc. Amer. Bull. 85, 1503-1514.
Irving, A.J., 1986. Polybaric magma mixing in alkali basalts and kimberlites: evidence from corundum, zircon and ilmenite megacrysts. 4th Int. Kimberlite Conf. Perth Geol. Soc. Aust. Abstr. Ser., vol. 16. Blackwell Scientific, Oxford, pp. 262-264.
Irving, A.J., Frey, F.A., 1984. Trace element abundances in megacrysts and their host basalts: constraints on partition coefficients and megacryst genesis. Geochim. Cosmochim. Acta 48, 1201-1221.
King, E.M., Valley, J.W., Davis, D.W., Kowallis, B.J., 2001. Empirical determination of oxygen isotope fractionation factors for titanite with respect to zircon and quartz. Geochim. Cosmochim. Acta 65, 3165-3175.
Levinson, A.A., Cook, F.A., 1994. Gem corundum in alkali basalt: origin and occurrence. Gems. Gemol. 30, 253-262.
Limtrakun, P., Khin Zaw, Ryan, C.G., Mernagh, T.P., 2001. Formation of the Denchai gem sapphires, northern Thailand: evidence from mineral chemistry and fluid/melt inclusion
characteristics. Mineral. Mag. 65, 737-748.
Liu, T.C., Presnall, D.C., 1990. Liquidus phase relationships on the join anorthite forsterite quartz at 20 kbar with applications to basalt petrogenesis and igneous sapphirine. Contrib. Mineral. Petrol. 104, 735-742.
Liu, T.C., Presnall, D.C., 2000. Liquidus phase relations in the system CaO-MgO-Al2O3-SiO2 at 2.0 GPa: applications to
basalt fractionation, eclogites, and igneous sapphirine. J. Petrol. 41, 3-20.
Mattey, D., Lowry, D., Macpherson, C., 1994. Oxygen isotope
composition of mantle peridotite. Earth Planet. Sci. Lett. 128, 231-241.
Mukasa, S.B., Fischer, G.M., Barr, S.M., 1996. The character of the subcontinental mantle in Southeast Asia: evidence from isotopic and elemental compositions of extension-related Cenozoic basalts in Thailand. Am. Geophys. Monogr. 95, 233-252.
Oakes, G.M., Barron, L.M., Lishmund, S.R., 1996. Alkali basalts and associated volcaniclastic rocks as a source of sapphire in eastern Australia. Aust. J. Earth Sci. 43, 289-298.
Osanai, Y., Hamamoto, T., Maishima, O., Kagami, H., 1998. Sapphirine- bearing granulites and related high-temperature metamorphic rocks from the Higo metamorphic terrane, westcentral Kyushu, Japan. J. Metamorph. Geol. 16, 53-66.
Reddy, K.P.R., Cooper, A.R., 1982. Oxygen diffusion in sapphire. J. Am. Ceram. Soc. 65, 634-638.
Sharp, Z.D., 1990. A laser-based microanalytical method for the in situ determination of oxygen isotope ratios of silicates and oxides. Geochim. Cosmochim. Acta 54, 1353-1357.
Sheppard, S.M.F., 1986. Igneous rocks: III. Isotopic case studies of magmatism in Africa, Eurasia and Oceanic Islands. In: Valley, J.W., Taylor Jr., H.P., ONeil, J.R. (Eds.), Stable Isotopes in High Temperature Geological Processes. Rev. Mineral., vol. 16. Mineralogical Society of America, Washington, DC, pp.319-371.
Spera, F.J., 1984. Carbon dioxide in petrogenesis: III. Role of volatiles in the ascent of alkaline magma with special reference to xenolith-bearing mafic lavas. Contrib. Mineral. Petrol. 88, 217-232.
Sutherland, F.L., Hoskin, P.W.O., Fanning, C.M., Coenraads, R.R., 1998. Models of corundum origin from alkali basaltic terrains: a reappraisal. Contrib. Mineral. Petrol. 133, 356-372.
Taylor Jr., H.P., 1968. The oxygen isotope geochemistry of igneous rocks. Contrib. Mineral. Petrol. 19, 1-71.
Upton, B.G.J., Hinton, R.W., Aspen, P., Finch, A., Valley, J.W., 1999. Megacrysts and associated xenoliths: evidence for migration of geochemically enriched melts in the upper mantle beneath Scotland. J. Petrol. 40, 935-956.
Valley, J.W., Matthew, N.M., Kohn, J., Niendorf, C.R., Spicuzza, M.J., 1995. UWG-2, a garnet standard for oxygen isotope ratios: strategies for high precision and accuracy with laser heating. Geochim. Cosmochim. Acta 59, 5223-5231.
Vichit, P., 1992. Gemstones in Thailand. In: Piancharoen, C. (Ed.), Supplementary Volume of Proceedings of a National Conference on Geologic Resources of Thailand: Potential for Future Development. Dept. Min. Res., Bangkok, Thailand, pp. 124-150.
Yui, T.F., 2000. Preliminary results on CO2 laser-fluorination system for O-isotope micro-analysis of silicate/oxide grain separates. J. Geol. Soc. China 43, 237-246.
Zhang, H.F., Mattey, D.P., Grassineau, N., Lowry, D., Brownless, M., Gurney, J.J., Menzies, M.A., 2000. Recent fluid processes in the Kaapvaal craton, South Africa: coupled oxygen isotope and trace element disequilibrium in polymict peridotites. Earth Planet. Sci. Lett. 176, 57-72.
Zheng, Y.F., 1991. Calculation of oxygen isotope fractionation in metal oxides. Geochim. Cosmochim. Acta 55, 2299-2307.
Zheng, Y.F., 1993. Calculation of oxygen isotope fractionation in anhydrous silicate minerals. Geochim. Cosmochim. Acta 57, 1079-1091." name="eprints.referencetext" />
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<meta content="Alluvial gem sapphires from the Denchai area, northern Thailand, have O-isotope compositions ranging from + 4.7 per mil to + 6.1 per mil(15 samples), with one outlier, + 8.4 per mil. It is suggested that these sapphires are not in O-isotope equilibrium with and must be xenocrysts from the nearby alkali basalts, which contain olivine phenocrysts with delta 18 O= + 4.9 per mil to + 5.1 per mil and are the presumed sources of these gem sapphires. Homogeneous delta 18 O values within individual sapphire crystal indicate limited interactions with the carrier magmas during transport to the surface. The O-isotope compositions of these sapphires suggest that crustal rocks might have been involved in the genesis of those sapphires with delta 18 O values higher than + 5.5 per mil. A hybrid origin model for the Denchai sapphires is, therefore, postulated, which involves different degrees of interactions between a fractionated partial melt from (metasomatized) mantle and a lower/mid-crust Al-rich rock." name="DC.description" />
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    <h1 class="ep_tm_pagetitle">Oxygen isotope composition of the Denchai sapphire, Thailand: a clue to its enigmatic origin</h1>
    <p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Yui, Tzen-Fu</span> and <span class="person_name">Zaw, K.</span> and <span class="person_name">Limtrakun, P.</span> (2003) <xhtml:em>Oxygen isotope composition of the Denchai sapphire, Thailand: a clue to its enigmatic origin.</xhtml:em> Lithos, 67 . pp. 153-161. ISSN 0024-4937</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/1877/1/Tzen-Fu%2C_Zaw_et_al_LITHOS_2003.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" class="ep_doc_icon" border="0" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/1877/1/Tzen-Fu%2C_Zaw_et_al_LITHOS_2003.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />173Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input accept-charset="utf-8" value="2360" name="docid" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1016/S0024-4937(02)00268-2">http://dx.doi.org/10.1016/S0024-4937(02)00268-2</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">Alluvial gem sapphires from the Denchai area, northern Thailand, have O-isotope compositions ranging from + 4.7 per mil to + 6.1 per mil(15 samples), with one outlier, + 8.4 per mil. It is suggested that these sapphires are not in O-isotope equilibrium with and must be xenocrysts from the nearby alkali basalts, which contain olivine phenocrysts with delta 18 O= + 4.9 per mil to + 5.1 per mil and are the presumed sources of these gem sapphires. Homogeneous delta 18 O values within individual sapphire crystal indicate limited interactions with the carrier magmas during transport to the surface. The O-isotope compositions of these sapphires suggest that crustal rocks might have been involved in the genesis of those sapphires with delta 18 O values higher than + 5.5 per mil. A hybrid origin model for the Denchai sapphires is, therefore, postulated, which involves different degrees of interactions between a fractionated partial melt from (metasomatized) mantle and a lower/mid-crust Al-rich rock.</p></div><table style="margin-bottom: 1em" cellpadding="3" class="not_ep_block" border="0"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Keywords:</th><td valign="top" class="ep_row">Gemfield; Sapphire; Oxygen isotope; Alkali basalt; Thailand</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/260100.html">260000 Earth Sciences &gt; 260100 Geology</a></td></tr><tr><th valign="top" class="ep_row">Collections:</th><td valign="top" class="ep_row">UNSPECIFIED</td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">1877</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Mrs Katrina Keep</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">06 Sep 2007</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">30 Jan 2008 15:27</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=1877;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&amp;eprintid=1877">item control page</a></p>
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